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X  $ 0{G   $ 3 BCDEF\Ԕ==zl.g9 d)K+:-&9E[j F Eo[  k,^=DH4M]p @#O(_5aDeeVP@, h @Mbq D QL3@3@\+,@                       $ 3 BUCDEFPԔ44U|\7  +;, ltr`Pc}f_LI::0"nua2eYnNIvgukUf%(@                 v ^  $ 6Hvy s  8a1 2 $ 6PvCj 8a2 2 $ 6 v+~  X qTu^l5ug 2 $ 6,v"< pAg-AgCl5ug 2 $l $ DA25%F l $ DA25% # FF r $ s *C"?`r $ s *C"?Jr $ s *C"?L LB $ c $D-- rR $ s *C"?c  H $ 0޽h ? ̙3380___PPT10.~   l d `)x (  x x 0v@@` .60t^N 9hncُNSt NNNp H5ug 2,R x s *f^B x 6D  ^B x 6D  ^B x 6D  ^B x 6D 0 ^B x 6D` ` ^B x 6D 0 F P `  x  p Z2 x s *P Z x s * `` ^B  x 6D) R !x s *p ( "x BClDEpF0l;\$ $&uhN+T-3`[Ay260 @         ? ( #x BCLDEpF0L8O^uwX p$wsabH; !@          j^B $x 6D0 @0 ^B %x 6D  ^B &x 6D @  'x 0v   2a1 2dB (x@ <D>0   )x 0 vp@  6a2 2H x 0޽h ? ̙33 p|(  | | 04v@ : Ǒ(uُNňn $NSk5ugv5uMO]NH+;m^vsQ|/f2 2  $ | <A }?? x }dAf | 0v`   D & 2  | 0p   D & 2 H | 0޽h ? ̙33y___PPT10Y+D=' = @B +V  } u   (    0@0 (:NNHNN*Nst[pHNuyrkT^ 2$ R  s *@` R  s *@   0   lJH+ Na+ H+ Na+ H+ Na+ H+ Na+ H+ Na+K 2               i  0Lm``d  1Na+ H+ Na+ Na+ H+ Na+ Na+ H+2 2          0-  Wa1H8 2     02P Wa2H8 2     06 9  `r^st 0.1mm (2 dB  <D>PdB  <D> P   0< P  nH+Sm]h^[ibce5uMO 2  H  0޽h ? ̙33y___PPT10Y+D=' = @B +:  "( ,, zl `P@{ G'J ,$D 0  <A "??P@ x "dAf   0M`P { S_[H+]>> [Na+] KH/Na bNaSN_eu. S_[Na+]Sm^_'Ye,Qs],y:N]. 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L TB , c $D- - zR , s *C"? f r2 , s *C"?}=LB , c $D , 0dڂ} <as 2$  , 0`ނ) @at  2$R !, s *c  ", 0s  Tst 2r #, s *C"?D  $, 3 BCDEF\Ԕ==zl.g9 d)K+:-&9E[j F Eo[  k,^=DH4M]p @#O(_5aDeeVP@, h @Mbq D QL3@3@\+,@                    p6  %, 3 BUCDEFPԔ44U|\7  +;, ltr`Pc}f_LI::0"nua2eYnNIvgukUf%(@                 s U  &, 0L q X qTu^l5ug 2 ', 0 ,  pAg-AgCl5ug 2 $4F J  (, s p|z ), s *C"? z *, s *C"? c z +, s *C"?J  z ,, s *C"? L TB -, c $D- - zR ., s *C"? f r2 /, s *C"?kLB 0, c $DF  , 1, 0T e <ax 2$ 2, 0PIW @at  2$  4,0 TA ? ?O ] i  dAfH , 0޽h ? ̙3380___PPT10./m TL@ 4(  4 4 0DZTz rnm;m^Kmϑ  hQReQl 2  40 TA ? ?$,}  dAf 4 0pj  t,KmϑagNW,gv T znm;m^W,g NS  2   4 0p v &1u$N!kKmϑv5uMO]SNBlQ*gwSm^CX& 2 H 4 0޽h ? ̙3380___PPT10.K p&2@(  @ @ 0/ h2 5uMOn[l 2 X @ 0`  LB @ c $D3 )LB @ c $D3 ` "LB @ c $DLB @ c $DgLB @ c $DM))LB @ c $DMgMR @ s *<gX @ 0`  LB @@ c $D)"R @ s *@ R @ s *@F R @ s *ymR @ s *\mR2 @ s *r  X @ 0pX @ 0X2 @ 0z CmLB @ c $Dp}LB @@ c $D}LB !@ c $DZpZLB "@ c $DpLB #@ c $DjpjLB $@ c $DpLB %@ c $DzpzLB &@ c $DpX '@ 0 ,LB (@ c $D   )@ BCDE@F A ,*.D@7N @     S" s i RB *@ s *DRB +@ s *D, -@ B CDELF$A}}(}" \g;MaO/ u }@      S"  t I .@ 0 ZE/mv 2 /@ 0 Y0 y 8V/ml 2 0@ 0$ q  : 2   1@0 TA ? ? p   dAfH @ 0޽h ? ̙3380___PPT10.^w  !'((  (r ( S h)wG   r ( S (*'G   RB ( s *DXRB ( s *D ^ ( 6TRB ( s *D  RB  ( s *DOL L _RB  ( s *DL m RB  ( s *DXX RB  ( s *Dm m b   (  B$ CcDEF`A@@9O>v=RJ>$(C3]@xRHG(81jAjA;8K <C9/- Fv+98,=Q(b~(BcJ=GcJA9"i- %xA;7(^2p91 2 \ x  ( $ -0@                     S" d Mj ^2 ( 6 SE RB ( s *D XX ^ ( 6 H^ ( 6 yH( ( c BvCMDE4FA SMKDSb\fk2'I<v @    S"  L ^2 ( 6  ^ ( 6 6w^2 ( 6vXB ( 0DS ( 6 1 u(  1V 2 ( 65   1A 2R ( s *f Z (  B$CDE4FA Npp1$}go$ @    S" %  ( BCQDE(FAA Q_i" @   S RB !( s *D RB "(@ s *DS  #( 0:   1i 2 $( 0>vY 1v 2 %( 0A) F1 P tR5uS 2  &( 0 = I  P [ER5uS 2  '( 0I z ` C |"S5uRR iRM mc5uMO 5uS 2 H ( 0޽h ? ̙33___PPT10i.[+D=' = @B +!   8 0 p (  p p 0pfl XN05uRgl 2   p 0s3g S N5uRg 2  p 0vz } v0c6R5uMO5uRg R`5uAm5uRg ^l4g5uRg 2 Xr p 0` 6r  p s *C"?s l X  p 0 1 vLB  p c $D   LB  p c $D  D R  p s *8 LB p c $D N X p 0& 4 t Xb p 0 N ^ LB p c $D N N LB p c $D 8 LB p@ c $D h LB p@ c $D hN X p 0T Kt  p 0H   J]\O5uS 2  p 0S tY  Jc6R5uS 2 RB p s *DCS RB p s *DCCXB p 0DC&  p <X  Xc6R5uMO5uRgl $ H p 0޽h ? ̙33___PPT10i.O+D=' = @B +Q h`  (   "   0 J>NO1.0 mol/L CuT0.01 mol/L AgvRy && 2 #.     0 TA$ z? ?  z dAf   0|z   ^AgvgQ5uMO 2    04}74  ^CuvgQ5uMO 2    0ȝS ds  2AgHQgQ0S_AgvSm^M10-6Me 5uMO:N2 2 6   09 gY p"CuN6q NgQ 0RRyvvv0 2H   0޽h ? ̙33___PPT10i.+D=' = @B +  x(  x x 0 7 < N0^NRgl ǏKmϑ5u-Nmv5uϑۏLRgvN{|el0( 2(  x 0`@` : 2    x0 TA ? ?@W   dAfn  x 0@@ k  xm  5ug NgQir(vϑ M  RP[ϑbSP[ϑ n  SN5ugS^v5uP[pe F  lb,{8^pe96486.7C/mol = 2=Z     x 0 G f c6R5uMO^NRg R`5uAm^NRg 2 Xr x 0 gHH x 0޽h ? ̙33___PPT10i.Q`vü+D=' = @B + P~(    0 TA X? ?& X dAf  NĎ??"6?@`NNN?Np  Tc6R5uMO^NRg     0Ȏ 7V  2S_tX'Ye ktQ\ kt>3,TNySN_eu 2L H  0޽h ? ̙33___PPT10i.];+D=' = @B +8  p 8(    0ю]7 zR`5uAm^NRg  ^Nn[ $  0T׎d v ^NlKm[Na3AsO3 AsO33- AsO43- + 2e 2Br- Br2 +2eV 2         QRB  s *Dg  g RB  s *D -M RB  s *D  Z H  0޽h ? ̙3380___PPT10.@S  \( 0A@   0tv $,{V g1Rgl N0g1lvb_b( 2    s Av ?http://www.chemistry.vt.edu/chem-ed/echem/graphics/dme.jpg@@ h  s ,A 5??@@  5H  0޽h ? ̙332 r( ̙33   0a@ |Cd2+v5u 5ugS^:N 2"    0F ,Cd2+ + 2e +Hg CdHg 2 2 *^B  6D@@ @x  0m @  lR N*N6k 1 5uMO\*g0RCdv؏S5uMO 2 Cd_Y؏S ibce5uAmNu 3 gPibce5uAmNu07 27p \  S A 7??0  7H  0޽h ? ̙33 C; (  8   0Z  s *    BCpDE@F pPX@` (0pppX 0 @        0 s   kYO5uAm ir2 2   0xP 07  ^5uAm NGS6k i 2   0<} p  zgPibce5uAm id2 2    0䂚 P 8 5i 2   0  <EV  2`B   0D  `B   0D`B   0D  0t `G Z&-0.2 -0.5 -1' 2'H  0޽h ? ̙33  @(  XB  0D` XB  0D `    BCDE(F> |XX00` @   P ^B  6D ^B @ 6D  0   PC02 2   0  5C 2  0T 0 5X 2^B  6D    0P  FDC& 2  0   FDX& 2  0{ y  $C0 5ughbSm^ C ,gSOnmSm^ 2,H  0޽h ? ̙33J (    <A '??p`x 'dAf  <A (?? x (dAf  0,   `S_5uMOۏNekX'Y 2    <A )??p P x )dAf  08p fُ/fg1[ϑRgvW@x0 2  H  0޽h ? ̙33~  ~(  6  0I >20gPibce5uAme z N N_-N]w KSNhNHNirt+TINP 2    $   0 TA ? ?;  dAf  0 ɚp  dIlkovice z 2    0 TA& ? ?m V   dAf  0͚   &Dibce|pe m^lnvAm t^lnv[}T 26Xr  0`6   08Ϛ ] V+ Ty:Nk~{8^pe 2 H  0޽h ? ̙3380___PPT10.)( PH (   0 ZA  ?AA ?    d  0ٚ<@ \ Z h:N^lgؚ^ 2  0ޚ) YI  l&[-N(ueggP5uAm/f&TSibcec6R0 2 H  0޽h ? ̙3380___PPT10.[ @ +(   P  + #"6w  q  6d?U ___PPT9 #-0.81 -1.35 -0.67 -1.10 -1.29 -0.24  " & & &&  $&$((q  6L?% U ___PPT9 #-0.64 -1.00 -0.44 -1.20 -1.20 +0.04  " & & &&  $&$((  6?U% ___PPT9ph -1.18 -0.72 -1.36 -1.45  " & & &  6 ?U ___PPT9ph -0.59 -1.0 -0.4 +0.02  " & & &  6|?U ___PPT9 Cd2+ Zn2+ Pb2+ Ni2+ Co2+ Cu2+X  " & & &&    $&$((((((  6!?PU _ 1M NH4Cl:  [  6X?% PURJB___PPT9$  1M KClF  " &"M  6 ?P% URJB___PPT9$  1M KCNH( " &  64?PU V ^~TN(-N    6:?PU NyP[  NB  S |PPNB  S |  NB  S |P NB  S |P  ( 0>,TY 6 N0JSl5uMOE1/2 JS\ؚY[^v5uMOy:NJSl5uMO06 2 $ ) 0C( Tb B mTnm-N gQyKmyP[ S_YR5uMOR0RgNKmir(vR5uMOe ُyir(O(Wn^l5ug N؏S Nuv^vg1l06qT5ughb~~gSv0R0R,{Nyir(vgQ5uMO0Ygnm-NQyir(vgQ5uMOv]'Y 1\SNR+R_0RQ*Nnpfvg1l0~ 2~ ~H  0޽h ? ̙3380___PPT10.; ht $( A~?x?xL   0d5, V0g1Rgvyrk'` 5ugvyrk'` 5uagNvyrk'` 10Sk5ugT]\O5ug5ugvyrk'` Sk5ug  qTu^l5ug by'Y05uAm[^\ ^\NSgS5ug ]\O5ug  n^l5ug by\05uAm[^'Y ^\gS5ugfr 2  +P Xr  0*}H  0޽h ? ̙33*  *(    s D0e0e #" 0ej   H  0޽h ? ̙3380___PPT10.Wh  (  p  0fZX2 205uagNvyrk'` yP[0R5ughbdibceY ؏ gyT[Am T$N^dS0 1 mdy5uAm  R/ec5u( O`lQ;S\ 5uSMNO0 2 md[Am5uAm  Ndbmd0 3 md'llTg1g'Y  r 2 $$ $t+  H  0޽h ? ̙33@  0( /   0xv@F < g1Rg؏ReQd'lBRThb;m'`BR Nd'lTmdg1g'Y0 28 0 @  0z0 FBO2 + 2 H+ + 2e H2O2 E = - 0.05V H2O2 + 2e +2H+ 2H2O E = - 0.9VC 2        fB  6D fB  6Dp   0  `` > XB  0D pXB  0D XB  0D  XB  0D    0̏ 5V 2  0  5i 2  0P  p  Vg1g'Y 2^B  6D  H  0޽h ? ̙33 f^@(    0  ^N0g1Rgv@\P ^l5ugvyr'`  5u[5uAmEQ5u5uAm S_e5uSe u^l5ug&^ck5u n^l5ug N&^5u u^l5ugTn^l5ugEQ5u NuEQ5u5uAm N5u㉹eTvS :NEQ5u5uAm0 S_5uS_'Ye u^l5ug&^5u b_bckEQ5u5uAm04r 2 ( ^$]H  0޽h ? ̙334 P+0t( {,? \  0ܦ F EQ5u5uAm'Y\:N10-7 A vS_N10-5 M /fcؚupOe^vx0L$ 2   F R2  s *pp`X  0)0pX  0)0pX  0) pR2  s *p  R2  s *p0   0  5+ 2  0`   5+ 2  0t @  5+ 2  0T `  5+ 2  0й @  5+ 2  0\`   5+ 2  0  5+ 2  00 P  5+ 2  0  @  5+ 2  0d 0  0  5+ 2  0 p  5+ 2  0| `  5+ 2  0 0  5+ 2  0X  @  5+ 2  00  P  5+ 2  0Dp` @  5+ 2  0p `  5+ 2  0\0 P  5+ 2  0 pP@  5+ 2  0H @   5+ 2  0x @   5+ 2  04 pP  5+ 2  0  @ 5+ 2  0 0 5+ 2 ! 0   5+ 2 " 0X pP  5+ 2 # 0   5+ 2 $ 0p   5+ 2 % 0 ` pP  5+ 2 + 0p$ @ @ 5+ 2 , 0'  5+ 2 - 0+  5+ 2 . 0Dp0  5+ 2 / 0D1@``  5+ 2 0 06   p" EQ5u5uAm'Y\N^lnu^ gsQ0 2H  0޽h ? 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L TB -, c $D- - zR ., s *C"? f r2 /, s *C"?kLB 0, c $DF  , 1, 0I| e <ax 2$ 2, 0M|IW @at  2$  4,0 TA ? ?@O ] i  |dAfH , 0޽h ? ̙3380___PPT10./m=  TL@ 4(  4 4 0T|ZTz rnm;m^Kmϑ  hQReQl 2  40 TA ? ?@?vu  |dAf 4 0LY|pj  t,KmϑagNW,gv T znm;m^W,g NS  2   4 0^|v &1u$N!kKmϑv5uMO]SNBlQ*gwSm^CX& 2 H 4 0޽h ? ̙33___PPT10i.K+D=' = @B +  p&2@(  @ @ 0d|/ h2 5uMOn[l 2 X @ 0`  LB @ c $D3 )LB @ c $D3 ` "LB @ c $DLB @ c $DgLB @ c $DM))LB @ c $DMgMR @ s *<gX @ 0`  LB @@ c $D)"R @ s *@ R @ s *@F R @ s *ymR @ s *\mR2 @ s *r  X @ 0pX @ 0X2 @ 0z CmLB @ c $Dp}LB @@ c $D}LB !@ c $DZpZLB "@ c $DpLB #@ c $DjpjLB $@ c $DpLB %@ c $DzpzLB &@ c $DpX '@ 0 ,LB (@ c $D   )@ BCDE@F A ,*.D@7N @     S" s i RB *@ s *DRB +@ s *D, -@ B CDELF$A}}(}" \g;MaO/ u }@      S"  t I .@ 0r| ZE/mv 2 /@ 0s|Y0 y 8V/ml 2 0@ 0{| q  : 2   1@0 TA ? ?@ p   |dAfH @ 0޽h ? ̙33___PPT10i.^+D=' = @B +w   !'((  (r ( S |@wG  | r ( S |@'G  | RB ( s *DXRB ( s *D ^ ( 6TRB ( s *D  RB  ( s *DOL L _RB  ( s *DL m RB  ( s *DXX RB  ( s *Dm m b   (  B$ CcDEF`A@@9O>v=RJ>$(C3]@xRHG(81jAjA;8K <C9/- Fv+98,=Q(b~(BcJ=GcJA9"i- %xA;7(^2p91 2 \ x  ( $ -0@                     S" d Mj ^2 ( 6 SE RB ( s *D XX ^ ( 6 H^ ( 6 yH( ( c BvCMDE4FA SMKDSb\fk2'I<v @    S"  L ^2 ( 6  ^ ( 6 6w^2 ( 6vXB ( 0DS ( 6| u(  1V 2 ( 6,|   1A 2R ( s *f Z (  B$CDE4FA Npp1$}go$ @    S" %  ( BCQDE(FAA Q_i" @   S RB !( s *D RB "(@ s *DS  #( 0|   1i 2 $( 0|vY 1v 2 %( 0L|) F1 P tR5uS 2  &( 0|| I  P [ER5uS 2  '( 0| z ` C |"S5uRR iRM mc5uMO 5uS 2 H ( 0޽h ? ̙33___PPT10i.[+D=' = @B +!   8 0 p (  p p 0d|fl XN05uRgl 2   p 0|3g S N5uRg 2  p 0|z } v0c6R5uMO5uRg R`5uAm5uRg ^l4g5uRg 2 Xr p 0` 6r  p s *C"?s l X  p 0 1 vLB  p c $D   LB  p c $D  D R  p s *8 LB p c $D N X p 0& 4 t Xb p 0 N ^ LB p c $D N N LB p c $D 8 LB p@ c $D h LB p@ c $D hN X p 0T Kt  p 0|   J]\O5uS 2  p 0|S tY  Jc6R5uS 2 RB p s *DCS RB p s *DCCXB p 0DC&  p <|  Xc6R5uMO5uRgl $ H p 0޽h ? ̙33___PPT10i.O+D=' = @B +Q  h`  (   "   0| J>NO1.0 mol/L CuT0.01 mol/L AgvRy && 2 #.     0 TA$ z? ?@2j  z |dAf   0|z   ^AgvgQ5uMO 2    0|}74  ^CuvgQ5uMO 2    0,|S ds  2AgHQgQ0S_AgvSm^M10-6Me 5uMO:N2 2 6   0||9 gY p"CuN6q NgQ 0RRyvvv0 2H   0޽h ? ̙33___PPT10i.+D=' = @B +   x(  x x 0|7 < N0^NRgl ǏKmϑ5u-Nmv5uϑۏLRgvN{|el0( 2(  x 0||@` : 2    x0 TA ? ?@   |dAfn  x 0@ k  xm  5ug NgQir(vϑ M  RP[ϑbSP[ϑ n  SN5ugS^v5uP[pe F  lb,{8^pe96486.7C/mol = 2=Z     x 0@  G f c6R5uMO^NRg R`5uAm^NRg 2 Xr x 0 gHH x 0޽h ? ̙33___PPT10i.Q`vü+D=' = @B +  P~(    0 TA X? ?@& X dAf  N??"6?@`NNN?Np  Tc6R5uMO^NRg     0 7V  2S_tX'Ye ktQ\ kt>3,TNySN_eu 2L H  0޽h ? ̙33___PPT10i.];+D=' = @B +8   p 8(    0]7 zR`5uAm^NRg  ^Nn[ $  0Hd v ^NlKm[Na3AsO3 AsO33- AsO43- + 2e 2Br- Br2 +2eV 2         QRB  s *Dg  g RB  s *D -M RB  s *D  Z H  0޽h ? ̙3380___PPT10.@S   \( 0A@   0/ $,{V g1Rgl N0g1lvb_b( 2    s Av ?http://www.chemistry.vt.edu/chem-ed/echem/graphics/dme.jpg@@ h  s ,A 5??@@  5H  0޽h ? ̙33y___PPT10Y+D=' = @B +2  r( ̙33   07@ |Cd2+v5u 5ugS^:N 2"    0: ,Cd2+ + 2e +Hg CdHg 2 2 *^B  6D@@ @x  0lA @  lR N*N6k 1 5uMO\*g0RCdv؏S5uMO 2 Cd_Y؏S ibce5uAmNu 3 gPibce5uAmNu07 27p \  S A 7??0  7H  0޽h ? ̙33   C; (  8   0Z  s *    BCpDE@F pPX@` (0pppX 0 @        0HK   kYO5uAm ir2 2   0PP 07  ^5uAm NGS6k i 2   0tU p  zgPibce5uAm id2 2    0Z P 8 5i 2   0] <EV  2`B   0D  `B   0D`B   0D  0db `G Z&-0.2 -0.5 -1' 2'H  0޽h ? ̙33y___PPT10Y+D=' = @B +   @(  XB  0D` XB  0D `    BCDE(F> |XX00` @   P ^B  6D ^B @ 6D  0i   PC02 2   0n  5C 2  0q 0 5X 2^B  6D    0kP  FDC& 2  0Dz   FDX& 2  0~ y  $C0 5ughbSm^ C ,gSOnmSm^ 2,H  0޽h ? ̙33y___PPT10Y+D=' = @B +  (    <A '??p`x 'dAf  <A (?? x (dAf  0(   `S_5uMOۏNekX'Y 2    <A )??p P x )dAf  0,p fُ/fg1[ϑRgvW@x0 2  H  0޽h ? ̙33y___PPT10Y+D=' = @B +   ~(  6  0I >20gPibce5uAme z N N_-N]w KSNhNHNirt+TINP 2    $   0 TA ? ?@[%*  dAf  0p  dIlkovice z 2    0 TA& ? ?@> V  dAf  0   &Dibce|pe m^lnvAm t^lnv[}T 26Xr  0`6   0ܠ ] V+ Ty:Nk~{8^pe 2 H  0޽h ? ̙33___PPT10i.)(+D=' = @B +9  PH (   0 ZA  ?AA ?@q    d  0<@ \ Z h:N^lgؚ^ 2  0@) YI  l&[-N(ueggP5uAm/f&TSibcec6R0 2 H  0޽h ? ̙33___PPT10i.[+D=' = @B +    @ -(   a0  -# #"6.8  q  6Ĵ?0 ___PPT9 #-0.81 -1.35 -0.67 -1.10 -1.29 -0.24  " & & &&  $&$((q  6? 0 ___PPT9 #-0.64 -1.00 -0.44 -1.20 -1.20 +0.04  " & & &&  $&$((  6Ȃ? 0 ___PPT9ph -1.18 -0.72 -1.36 -1.45  " & & &  6Ԃ?f0 ___PPT9ph -0.59 -1.0 -0.4 +0.02  " & & &  6<܂?af0 ___PPT9 Cd2+ Zn2+ Pb2+ Ni2+ Co2+ Cu2+X  " & & &&    $&$((((((  60? _ 1M NH4Cl:  [  6 ? 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